The Plastic Chemicals Hiding in Your Food

作者:Brigade  于 2024-1-7 05:27 发表于 最热闹的华人社交网络--贝壳村

作者分类:转文|通用分类:流水日记|已有3评论

group of various foods (condiments, meats, vegetables, cheeses, etc) in plastic, metal, and paper packagingPhoto: Sarah Anne Ward

By the time you open a container of yogurt, the food has taken a long journey to reach your spoon. You may have some idea of that journey: From cow to processing to packaging to store shelves. But at each step, there is a chance for a little something extra to sneak in, a stowaway of sorts that shouldn’t be there.

That unexpected ingredient is something called a plasticizer: a chemical used to make plastic more flexible and durable. Today, plasticizers—the most common of which are called phthalates—show up inside almost all of us, right along with other chemicals found in plastic, including bisphenols such as BPA. These have been linked to a long list of health concerns, even at very low levels.

Consumer Reports has investigated bisphenols and phthalates in food and food packaging a few times over the past 25 years. In our new tests, we checked a wider variety of foods to see how much of the chemicals Americans actually consume. The answer? Quite a lot. Our tests of nearly 100 foods found that despite growing evidence of potential health threats, bisphenols and phthalates remain widespread in our food.

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The Problem With Plastic Chemicals

Bisphenols and phthalates in our food are concerning for several reasons.

To start, growing research shows that they are endocrine disruptors, which means that they can interfere with the production and regulation of estrogen and other hormones. Even minor disruptions in hormone levels can contribute to an increased risk of several health problems, including diabetes, obesity, cardiovascular disease, certain cancers, birth defects, premature birth, neurodevelopmental disorders, and infertility.

Those problems typically develop slowly, sometimes over decades, says Philip Landrigan, MD, a pediatrician and the director of the Program for Global Public Health and the Common Good at Boston College. "Unlike a plane crash, where everyone dies at once, the people who die from these die over many years."

Another concern is that with plastic so ubiquitous in food and elsewhere, the chemicals can’t be completely avoided. And though the human body is pretty good at eliminating bisphenols and phthalates from our systems, our constant exposure to them means that they enter our blood and tissue almost as quickly as they’re eliminated. And plasticizers in particular can easily leach out of plastic and other materials. In addition, the chemicals’ harmful effects may be cumulative, so steady exposure to even very small amounts over time could increase health risks.

All that makes it difficult to trace any particular bad health outcome—say, a heart attack or breast cancer—to the chemicals. And it makes it hard for regulators to set a limit for what is considered safe for any food. "As a first step, the key is to determine how widespread the chemicals are in our food supply," Rogers says. "Then we can develop strategies, as a society and individually, to limit our exposure."

High Risks Even at Low Levels

To help figure out the scope of the problem, CR tested a wide range of food items, in a variety of packaging.

Specifically, we tested 85 foods, analyzing two or three samples of each. We looked for common bisphenols and phthalates, as well as some chemicals that are used to replace them. (Read more about these chemical substitutes.) We included prepared meals, fruits and vegetables, milk and other dairy products, baby food, fast food, meat, and seafood, all packaged in cans, pouches, foil, or other material.

The news on BPA and other bisphenols was somewhat reassuring: While we detected them in 79 percent of the tested samples, levels were notably lower than when we last tested for BPA, in 2009, "suggesting that we are at least moving in the right direction on bisphenols," says CR’s Rogers.

But there wasn’t any good news on phthalates: We found them in all but one food (Polar raspberry lime seltzer). And the levels were much higher than for bisphenols.

Determining an acceptable level for these chemicals in food is tricky. Regulators in the U.S. and Europe have set thresholds for only bisphenol A (BPA) and a few phthalates, and none of the foods CR tested had amounts exceeding those limits.

But "many of these thresholds do not reflect the most current scientific knowledge, and may not protect against all the potential health effects," says Tunde Akinleye, the CR scientist who oversaw CR’s tests. "We don’t feel comfortable saying these levels are okay," he says. "They’re not."

The decision to allow these chemicals in food "is not evidence-based," says Ami Zota, ScD, an associate professor of environmental health sciences at the Columbia University Mailman School of Public Health in New York City, who has studied the risks of phthalates.

For example, one of the most well-studied phthalates is called DEHP. Studies have linked it to insulin resistancehigh blood pressure, reproductive issues, early menopause, and other concerns at levels well below the limits set by American and European regulators. It was the most common phthalate that we found in our tests, with more than half of the products we tested having levels above what research has linked to health problems.

In addition, Akinleye says that with exposure to these chemicals coming from so many sources—not only food but also other products, such as printed receipts and household dust— it’s difficult to quantify what a "safe" limit would be for a single food. "The more we learn about these chemicals, including how widespread they are, the more it seems clear that they can harm us even at very low levels," he says.

Plastic Chemicals in Foods: What Our Tests Found

The 67 grocery store foods and 18 fast foods CR tested are listed in order of total phthalates per serving. While there is no level that scientists have confirmed as safe, lower levels are better. Our results show that although the chemicals are widespread in our food, levels can vary dramatically even among similar products, so in some cases you may be able to use our chart to choose products with lower levels.

BEVERAGES
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Brisk Iced Tea Lemon (can)
7,467
 
Coca-Cola Original (plastic)
6,167
 
Lipton Diet Green Tea Citrus (plastic)
4,433
 
Poland Spring 100% Natural Spring Water (plastic)
4,217
 
Juicy Juice 100% Juice Apple (plastic)
3,348
 
Pepsi Cola (can)
2,938
 
Juicy Juice 100% Juice Apple (cardboard box)
2,260
 
Gatorade Frost Thirst Quencher Glacier Freeze (plastic)
1,752
 
Polar Seltzer Raspberry Lime (can)
0
 
Canned Beans
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Hormel Chili With Beans (can)
9,847
 
Bush’s Chili Red Beans Mild Chili Sauce (can)
6,405
 
Great Value (Walmart) Baked Beans Original (can)
6,184
 
Bush’s Baked Beans Original (can)
3,709
 
Condiments
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Mrs. Butterworth’s Syrup Original (plastic)
1,010
 
Hunt’s Tomato Ketchup (plastic)
574
 
Sweet Baby Ray’s Barbecue Sauce Original (plastic)
22
 
Dairy
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Fairlife Core Power High Protein Milk Shake Chocolate (plastic)
20,452
 
SlimFast High Protein Meal Replacement Shake Creamy Chocolate (plastic)
16,916
 
Yoplait Original Low Fat Yogurt French Vanilla (plastic)
10,948
 
Tuscan Dairy Farms Whole Milk (plastic)
10,932
 
Ben & Jerry’s Ice Cream Vanilla (paperboard carton)
6,387
 
Wholesome Pantry (ShopRite) Organic Whole Milk (carton)
4,620
 
Great Value (Walmart) Ice Cream Homestyle Vanilla (paperboard)
3,068
 
Jell-O Pudding Snacks Original Chocolate (plastic)
1,756
 
Sargento Sliced Natural Cheddar Cheese Sharp (plastic)
1,481
 
Land O’Lakes Butter Salted (paper wrap/cardboard)
581
 
Fast Food
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Wendy’s Crispy Chicken Nuggets (paperboard)
33,980
 
Moe’s Southwest Grill Chicken Burrito (aluminum foil)
24,330
 
Chipotle Chicken Burrito (aluminum foil)
20,579
 
Burger King Whopper With Cheese (paper)
20,167
 
Burger King Chicken Nuggets (paper bag)
19,782
 
Wendy’s Dave’s Single With Cheese (aluminum foil/paper wrap)
19,520
 
McDonald’s Quarter Pounder With Cheese (cardboard)
9,956
 
Wendy’s Natural-Cut French Fries (paperboard)
8,876
 
Burger King Classic French Fries (paperboard)
8,512
 
McDonald’s Chicken McNuggets (cardboard)
8,030
 
Little Caesars Classic Cheese Pizza (cardboard box)
5,703
 
McDonald’s French Fries (paperboard)
5,538
 
McDonald’s Quarter Pounder Hamburger Patty (varied)
5,428
 
Taco Bell Chicken Burrito (paper wrap)
4,720
 
Domino’s Hand Tossed Cheese Pizza (cardboard box)
4,356
 
Wendy’s Dave’s Single Hamburger Patty (varied)
3,629
 
Burger King Whopper Hamburger Patty (varied)
2,870
 
Pizza Hut Original Cheese Pan Pizza (cardboard box)
2,718
 
Grains
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
General Mills Cheerios Original (paperboard box with plastic bag inside)
10,980
 
Success 10 Minute Boil-in-Bag White Rice (paperboard box with plastic bag insdie)
4,308
 
Pepperidge Farm Farmhouse Hearty White Bread (plastic bag)
2,184
 
Infant Food
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Gerber Mealtime for Baby Harvest Turkey Dinner (glass with lined lid)
4,267
 
Similac Advance Infant Milk-Based Powder Formula (can)
4,202
 
Beech-Nut Fruities Pouch Pear, Banana & Raspberries (pouch)
2,826
 
Gerber Cereal for Baby Rice (plastic)
1,599
 
Happy Baby Organics Clearly Crafted Banana & Strawberries (glass with lined lid)
1,300
 
Happy Baby Organic Milk-Based Infant Powder Formula With Iron (plastic)
977
 
Gerber Organic for Baby Pouch Apple Zucchini Spinach Strawberry (pouch)
706
 
Meat and Poultry
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Perdue Ground Chicken Breast (plastic)
9,985
 
Trader Joe’s Ground Pork 80% Lean 20% Fat (plastic wrap)
5,503
 
Premio Foods Sweet Italian Sausage (foam tray with plastic wrap)
4,725
 
Libby’s Corned Beef (can)
4,088
 
Bar S Chicken Jumbo Franks (plastic)
3,295
 
Stop & Shop Ground Beef 80% Lean 20% Fat (foam tray with plastic wrap)
2,729
 
Applegate Naturals Oven Roasted Turkey Breast (plastic)
2,295
 
Swanson White Premium Chunk Chicken Breast (can)
1,376
 
Johnsonville Smoked Sausage Beef Hot Links (plastic)
912
 
Packaged Fruits and Vegetables
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Del Monte Sliced Peaches in 100% Fruit Juice (can)
24,928
 
Green Giant Cream Style Sweet Corn (can)
7,603
 
Del Monte Fresh Cut Italian Green Beans (can)
5,264
 
Progresso Vegetable Classics Vegetable Soup (can)
2,888
 
Birds Eye Steamfresh Cut Green Beans (plastic bag)
907
 
Hunt’s Tomato Sauce (can)
680
 
Prepared Meals
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Annie’s Organic Cheesy Ravioli (can)
53,579
 
Chef Boyardee Beefaroni Pasta in Tomato and Meat Sauce (can)
13,628
 
Banquet Chicken Pot Pie (paperboard)
12,494
 
Campbell’s Chunky Classic Chicken Noodle Soup (plastic)
6,768
 
Chef Boyardee Big Bowl Beefaroni Pasta in Meat Sauce (plastic)
5,064
 
Campbell’s Chicken Noodle Soup (can)
2,848
 
Red Baron Brick Oven Cheese-Trio Pizza (paperboard box with plastic wrap inside)
1,707
 
Seafood
TOTAL PHTHALATES PER SERVING (NANOGRAMS)*
 
Chicken of the Sea Pink Salmon in Water Skinless Boneless (can)
24,321
 
King Oscar Wild Caught Sardines in Extra Virgin Olive Oil (can)
7,792
 
Snow’s Chopped Clams (can)
4,380
 
StarKist Wild Caught Light Tuna in Water (pouch)
1,735
 
StarKist Chunk Light Tuna in Water (can)
1,687
 
Season Brand Sardines in Water Skinless & Boneless (can)
1,258
 
*Includes the 10 phthalates we tested for: BBP, DBP, DiBP, DCHP, DEP, DEHP, DnHP, DMP, DiNP, and DNOP. We also tested for three chemicals used as phthalate substitutes (DEHA, DEHT, and DINCH), and three bisphenols (BPA, BPS, and BPF), which are not shown in this chart.
Making Food Safer

Growing concerns about the health risks posed by these chemicals have led U.S. regulators to meaningfully curtail the use of these chemicals in a number of products—but not yet food.

For example, the federal government has banned eight phthalates in children’s toys. But, with the exception of a 2012 ban on BPA in baby bottles (extended in 2013 to infant formula cans), there are no substantive limits on plastic-related chemicals in food packaging or production. Although the Food and Drug Administration no longer allows certain phthalates in materials that come into contact with food, the agency updated its regulations only after those chemicals were no longer in use. And just last year, it rejected an appeal from several groups calling for a ban on multiple phthalates used in materials that come into contact with food.

An FDA spokesperson told CR that in 2022 it asked the food industry and others to provide the agency with additional data about the use of plasticizers in any material that comes into contact with food during production, and might use that information to update its safety assessments of the chemicals.

CR’s food safety scientists and others say such a reassessment by the FDA and other agencies is overdue and essential. “Since bisphenols and phthalates are hazardous chemicals, they should not be allowed at all in food-contact materials,” says Erika Schreder, the science director at Toxic-Free Future, an advocacy group.

Supermarket and fast-food chains, as well as food manufacturers, should also be required to take action, Rogers says, and should set specific goals for reducing and eliminating bisphenols and phthalates from all food packaging and processing equipment throughout their supply chains.

CR contacted certain companies in our tests that had products with the highest phthalate levels per serving, and asked them to comment on our results. Annie’s, Burger King, Fairlife, Little Caesars, Moe’s Southwest Grill, Wendy’s, and Yoplait did not respond to our requests for comment.

Del Monte, Gerber, and McDonald’s emphasized that they abide by existing regulations. Gerber added that it requires its suppliers to certify that its food packaging is free of BPA and phthalates. Chicken of the Sea said it requires its suppliers to certify that neither products nor packaging has intentionally added BPA or phthalates, but it acknowledged that fish live in water that is often polluted with phthalates.

More chemical companies need to step up, too, by creating safer, more sustainable materials. "We want things to be functional, but also nontoxic and biodegradable and renewable," says Hanno Erythropel, PhD, at the Center for Green Chemistry and Green Engineering at Yale University in New Haven, Conn.

That may be tough, he acknowledges, but it should be possible: An entire field called green chemistry is working to develop just these sorts of alternatives.

In the meantime, see our advice on what you can do now to limit your exposure to these chemicals.

 
CR Fights to Get Plastic Chemicals
Out of Our Food, 1998-2024
 
June
1998

CR finds plasticizer chemicals called phthalates in some plastic wraps and cheeses, and asks the FDA to eliminate the chemicals from the food supply.

 
May
1999

CR finds that BPA in plastic baby bottles can leach into infant formula and advises parents to throw away bottles that could contain the chemical.

 
December
2009

CR finds BPA in nearly all 19 tested foods and calls on government agencies to eliminate the chemical in materials that come in contact with food.

 
October
2012

CR praises the FDA for banning BPA in baby bottles and sippy cups but calls on the agency to also ban the chemicals in infant formula containers and food cans. The FDA does so the following year.

 
August
2023

CR does not find BPA, lead, or certain phthalates in nine baby bottles but warns that related chemicals could still be present and cautions parents to consider using glass or silicone bottles.

 
January
2024

CR finds phthalates and related chemicals in nearly all 85 foods tested and calls on the FDA to get the chemicals out of food.

Editor’s Note: A version of this article published in the February 2024 issue of Consumer Reports Magazine incorrectly identified one of the products. It should have been Brisk Iced Tea lemon, not Lipton Brisk Lemonade. In addition, the package descriptions for several products in the chart of tested products have been changed to more accurately describe the materials used.



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回复 Brigade 2024-1-7 05:28
https://www.consumerreports.org/health/food-contaminants/the-plastic-chemicals-hiding-in-your-food-a7358224781/
回复 Brigade 2024-1-9 09:11
研究称美国瓶装水中发现大量纳米塑料碎片,每升11万

科学家利用激光对瓶装水中数十万个以前看不见的微小塑料颗粒进行了成像。Naixin Qian, 哥伦比亚大学


北京时间1月9日凌晨,国际学术期刊《美国国家科学院院刊》(PNAS)在线发表的一项最新研究称,使用最新的检测技术,研究人员在美国三种畅销瓶装水中发现大量微小塑料颗粒:每升瓶装水中发现了11万-37万个塑料颗粒。其中,90%的塑料颗粒小于1微米,被称为纳米塑料。它们在此前的检测中被忽视。
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研究人员未透露这些瓶装水的具体品牌。

该论文的标题是《利用SRS显微镜对纳米塑料进行快速单颗粒化学成像》(Rapid single-particle chemical imaging of nanoplastics by SRS microscopy)。

纳米塑料与微塑料不同。因为纳米塑料更加微小,它们可以通过肠道或肺部细胞,进入血液,甚至抵达心脏和大脑。纳米塑料甚至会穿过胎盘,进入胎儿体内。

人类头发的直径约为70微米。微塑料被定义为尺寸从5毫米到1微米的塑料碎片。而纳米塑料是尺寸小于1微米的颗粒,以十亿分之一米为单位进行测量。

从极地冰层到土壤、饮用水和食物,研究人员称,“有一个巨大的纳米塑料世界有待研究。”

2018年的一项研究发现,瓶装水中的塑料颗粒含量达平均每升含有325个。

但最新发表的这项新研究使用了一种被称为受激拉曼散射显微镜(SRS)的检测技术。两束被调谐的激光使特定分子共振,来探测样品。研究人员还计划用该技术来检测自来水。他们还将与环境健康专家合作,测量各种人体组织中的纳米塑料,并检查它们对发育和神经系统的影响。

全球每年的塑料产量接近4亿吨。每年有超过3000万吨的塑料被倾倒在水中或陆地上。许多由塑料制成的产品,包括合成纺织品,在使用过程中会脱落塑料颗粒。与天然有机物不同,大多数塑料不会分解成相对良性的物质。它们只是分裂成具有相同化学成分的越来越小的颗粒。除了单分子之外,理论上它们的大小没有限制。

研究人员确定了前述瓶装水中7种特定的纳米塑料颗粒,比如聚苯乙烯、聚氯乙烯、PET(聚对苯二甲酸乙二醇酯)、聚酰胺(一种尼龙)等。

聚酰胺颗粒可能来自装瓶前用于过滤净化水的塑料过滤器,这种颗粒的数量超过了PET。

PET是很多塑料瓶的材料。当瓶子受到挤压或受热时,塑料颗粒可能脱落而进入水中。当人们反复打开或关闭盖子时,磨损产生的塑料颗粒也会进入水中。

一个令人不安的消息是,研究人员寻找到7种塑料颗粒类型仅占他们在样本中发现的所有纳米颗粒的10%左右。而其余的塑料颗粒是什么,人们还不知道。
回复 Brigade 2024-1-17 21:38
https://www.pnas.org/doi/10.1073/pnas.2300582121

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