就朱令头发分析给《国际法医》编辑部的信(稿)

作者:赛昆  于 2024-1-7 05:00 发表于 最热闹的华人社交网络--贝壳村

作者分类:a|通用分类:热点杂谈|已有5评论

下面是俺给《国际法医》编辑部的信稿。摘译如下。
Ash and He (2018)文中的图2A展示了1994年所收集的受害者一根头发的生长历史。根据该图,头发生长了171天;而根据第4.3节,朱女士“当年年底完全秃顶”(1994年)。根据这些信息很容易计算出:该头发开始生长的第一天是7月14日,而第一个峰值在第19天,即8月2日,受害者当天居家。
但是,该文图五却将峰值日期移至8月下旬受害者从家返校后,与图2A相矛盾。希望通讯作者可以出来解释一下,为什么要不顾与图2的矛盾而把峰值日期后延。
即使以(均值+2×标准差)来计算,也不难得出这根头发从8月9日开始生长的结论,而此时头发的含铊量已经超过正常上限。也就是说,受害者有超过97.8%的可能于8月9日居家时中毒。
已有网友指出:这篇文章的分析还表明,凶手下毒用的是工业铊盐(含铅)而非学校实验室的铊溶液,因为通常学校实验室溶液是纯物质。

下面是原文。
另外补充一点:清华可以查一下当年童爱军实验组的铊溶液是否含铅(这句不在信中)。

A letter to the Editorial Board of "Forensic Science International"

Regarding Richard David Ash and Min He (2018), Details of a thallium poisoning case revealed by single hair analysis
using laser ablation inductively coupled plasma mass spectrometry, Forensic Science International, Vol. 292, 224–231

A 21-year-old Chinese lady, Miss Zhu, was poisoned in 1994.

Figure 2A in Ash and He (2018) provides a scientific presentation for the growth history of a piece of hair from the victim collected in 1994.

According to Figure 2A, the hair grew for 171 days. According to Section 4.3, Miss Zhu was "completely bald at the end of that year" (1994).  It can be easily calculated that the first day of that hair started to grow on July 14. That is, based on the information given in Figure 2A and Section 4.3, "Day 1" of ZHU1995H9 (hair ID) is July 14 and Day 171 is December 31.

The first peak is 152 days from the end of the year, and August 1 is 153 days from the end of the year. Therefore the first peak should be on August 2 and the victim was at home that day.

But Figure 5 of the article moves the peak to late August after Miss Zhu returned to school from home. This contradicts with Figure 2A and Section 4.3. The second author who "conducted the interpretation" converted Figure 2A to Figure 5.
 
Even if we assume the very fast case of 7/ (0.0411 +2*0.0053)=136 (days), we still can conclude that the victim was poisoned at home. It is well known that Miss Zhu lost all her hair on December 23, 1994 when she was hospitalized. With the assumption that the hair growth period be 136 days, the hair started to grow on August 9 when she was at home. It should be noted that she was already poisoned on that day, since the amount of thallium exceeded the safety limit of 10ng/g on Day 1 of the hair [1].

In China, many people accuse Zhu's classmate Miss Sun as the "only suspect". One main reason is that Sun could "legally handle thallium solution" since Sun joined a research group in the school lab starting in September 1994. The above mentioned analyses show that it is very unlikely that Zhu was poisoned only after September 1994.

Another finding from the article by Ash and He (2018) is that Zhu was poisoned with both thallium and lead. On the internet, somebody already pointed out that this shows that the thallium must be from industrial world and could not be from a university lab. Usually, in a school lab, the substance should be pure.

In conclusion, the victim was very likely (with >97.8% chance) to be poisoned at home and the thallium must be from industrial world. The second author for some reason moved the date of the first peak after August 15 and should explain this.

Reference
[1] Queirolo F., Stegen S., Contreras-Ortega C., Ostapczuk P., Queirolo A., Paredes B. Thallium levels and bioaccumulation in environmental samples of Northern Chile: human health risks. J. Chil. Chem. Soc. 2009;54(4):464–469

附图。
原文图2A:

原文图5(图中直线和中文是俺加的):作者把峰值后移,想遮掩真凶?







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发表评论 评论 (5 个评论)

5 回复 kyotosizumoto 2024-1-7 22:52
第一次看你的博客,我断定:
第一作者肯定不是北京人,因为北京学生喜欢暑假住在学校宿舍,自由。家里几乎没地方,只有周末才回家。何况当时朱令和黄开胜暑假方便继续在校谈恋爱和游泳等等。
第二作者肯定不是清华人,因为清华学生都知道9月选课进入实验室,必须在6-8月份提前进入熟悉环境和操作。
希望你不是给孙维洗地的。
感兴趣的话,看一下我明天首发的节目:
https://www.youtube.com/watch?v=OO-wa1OWD80
新證據讓朱令在家中毒說徹底破產(2024.01.08)
回复 赛昆 2024-1-8 00:14
kyotosizumoto: 第一次看你的博客,我断定:
第一作者肯定不是北京人,因为北京学生喜欢暑假住在学校宿舍,自由。家里几乎没地方,只有周末才回家。何况当时朱令和黄开胜暑假方
连原文都没看就来反驳。能看到原文?
原文说了,朱令在8月中才回校,此前居家。认识“Home"字吧?
又把“进入实验室”时间提前了。墙内报道过,“1994年9月”孙某进组,俺的其他博文有截屏。
替真凶遮掩真是辛苦,谣言要不断改。
最开始“动机”是“争演出”,后来不得不承认“我和三年前的判断也有不同“…
回复 scripting 2024-1-8 01:02
问题尖锐,提到点子上了。大部分网友是墙倒众人推的架势,已经丧失了独立思维的能力。
回复 kyotosizumoto 2024-1-8 19:51
赛昆: 连原文都没看就来反驳。能看到原文?
原文说了,朱令在8月中才回校,此前居家。认识“Home"字吧?
又把“进入实验室”时间提前了。墙内报道过,“1994年9月
哈哈哈。。。。。你真嫩!
求“朱令在家中毒”的犯罪嫌疑人?
答:因为朱令7月1日到9月5日全部“在家”24小时就没出门、游泳也在家、乐队排练也在家、和黄开胜见面也在家。。。。。可见朱令中毒的犯罪嫌疑人就是朱令的父母!!!
那么接着告诉我游泳池建在朱令家的家里吗?乐队全员来朱令家排练吗?黄开胜天天来朱令家见面吗?
回复 赛昆 2024-1-10 01:04
kyotosizumoto: 哈哈哈。。。。。你真嫩!
求“朱令在家中毒”的犯罪嫌疑人?
答:因为朱令7月1日到9月5日全部“在家”24小时就没出门、游泳也在家、乐队排练也在家、和黄开胜见
不识字?
原图五已经表示:8月15日前朱令在家。此后回校。

此信是请作者回答:为何把峰值日期画在“回校”期间,这个结论与图二矛盾。
对此,有问题?别扯什么游泳此。

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